Hello again James,
Unfortunately, PhotoComposer will not allow one photo to be seen "through" another. You could use PhD's background removal too to remove the background and leave only the sunspots, but that will introduce other complications.
The two options I suggested will suit your purposes better.
Using Power Director and chroma key is the simplest way to do it. Just overlay your photos, apply chroma key and take a snapshot of the screen.
The software I used to make the transparency was Paint.NET. It's free and easy to use. There are quite a few YouTube tutorials on applying transparency using Paint.NET that will help. Here's one
http://youtu.be/6OLKfRILqBM
PIX
PIX YouTube channel