have you tried the audio analysis?
I do a lot of music videos and it takes some doing to align the video to a separate audio track.
I just bought PD12 to see if it works for me. I have been using Adobe Premiere 10. What I do there is to click on the audio track that is in the video and make it large and do the same with the separate audio track. I then expand the time line so that both audio tracks can be seen better. I then try to see if I can find a place in the video where someone is making a movement that has sound too and try to get the separate audio in line with that, eg someone raises their hand and you can hear the song on the video audio and find a spot on the separate audio where you get that same sound. In Premiere I could highlight a track and hold doen the alt key and tap on the arrow keys to move that track one frame at a time. it takes some doing you can get almost frame accurate. So far in PD12 I see where you can put a time line marker on that hand raising and one where you think the serarate audio is at and then go up to audio analysis and align by menu markers.
this is a rough idea and I hope it may help until someone here can help you more.
good luck and let me know it any of this makes enough sense to help and we can go from there.